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data-mce-style="color: #000000; font-family: arial, helvetica,
sans-serif; font-size: 12pt;"><img
data-mce-src="https://mail.cdu.gov.hr/service/home/~/?auth=co&loc=hr&id=22177&part=1.2.2"
src="cid:part1.PXrAqSvR.0vb7x6NL@ifs.hr" class="" width="321"
height="70"><span> </span></span><br>
Thursday 15th June 2023 at 11:00, IF 1st wing, big lecture hall <br>
<span style="color: #55913c; font-family: times new roman, new
york, times, serif;"><span style="font-size: 21.3333px;"
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lang="EN-GB">Microscopic
investigation of intrinsic defects in transition metal
dichalcogenide
monolayers grown by chemical vapour deposition</span></b></b></span></span><!--[if gte mso 9]><xml>
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<div><span style="color: #55913c; font-family: times new roman,
new york, times, serif;"><span style="font-size: 21.3333px;"
data-mce-style="font-size: 21.3333px;"></span></span><span
style="color: #55913c; font-family: times new roman, new york,
times, serif;"><span style="font-size: 21.3333px;"
data-mce-style="font-size: 21.3333px;"></span></span><span
style="color: #55913c; font-family: times new roman, new york,
times, serif;"><span style="font-size: 21.3333px;"
data-mce-style="font-size: 21.3333px;"></span></span><span
style="color: #55913c; font-family: times new roman, new york,
times, serif;"><span style="font-size: 21.3333px;"
data-mce-style="font-size: 21.3333px;"></span></span></div>
<div><b style="color: #000000; font-family: arial, helvetica,
sans-serif; font-size: 18.6667px;" data-mce-style="color:
#000000; font-family: arial, helvetica, sans-serif; font-size:
18.6667px;">mag. phys. Ana Senkić</b><br>
</div>
<div><span style="font-family: sans-serif;"><span
style="font-size: 14.6667px;" data-mce-style="font-size:
14.6667px;"><b>Institue of Physics, Zagreb<br>
</b></span></span></div>
<div style="color: #000000; font-family: arial, helvetica,
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</div>
</div>
</div>
<div style="color: #000000; font-family: arial, helvetica,
sans-serif; font-size: 16px; font-style: normal;
font-variant-ligatures: normal; font-variant-caps: normal;
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<div align="justify">
<p class="MsoNoSpacing" style="text-align:justify"><span
style="mso-ansi-language:EN-GB" lang="EN-GB">Transition
metal dichalcogenides (TMDs) present
a broad family of two-dimensional (2D) materials with
properties ranging from
insulators to superconductors. With the general formula of
MX<sub>2</sub>, the
monolayer (1L) material consists of one plane of transition
metal atoms M which
is sandwiched between two planes of chalcogen atoms X. The
most investigated
TMD material is molybdenum disulfide – MoS<sub>2</sub>. This
semiconductor has
a bandgap in the visible spectrum, making it a promising
candidate for
application in photovoltaics, solar cells, optoelectronics,
field effect
transistors [1-3]. Due to its 2D nature, MoS<sub>2</sub> is
extremely
susceptible to the environment: humidity, temperature,
exposure to atmosphere [4].
For these reasons, the synthesis of high-quality
monocrystals with
non-deteriorating properties, is of great importance.
Optimum synthesis
conditions yield high-quality crystalline structure, which
then in turn, leads
to great properties – such as optical and electronic.</span></p>
<p class="MsoNoSpacing" style="text-align:justify"><span
style="mso-ansi-language:EN-GB" lang="EN-GB">In the first
part of my seminar I will discuss
how different synthesis parameters influence the morphology
and optical
properties of MoS<sub>2</sub> samples [6]. In the second
part, I will present
the results of a detailed study on two different MoS<sub>2</sub>
samples,
synthesized under different growth temperatures, in order to
understand the
correlation between growth temperature and defects’ nature
of the samples [6].
The influence of defects on optical and electronic
properties is investigated
with low-temperature photoluminescence measurements,
room-temperature transient
absorption microscopy, and Kelvin Probe Force Microscopy. In
the final part of
my talk, I will discuss how defects can be utilised in order
to produce new
properties in a host material via alloying and how
apparently identical growth
conditions can lead to different crystal structures.</span></p>
<p class="MsoNoSpacing" style="text-align:justify"><b
style="mso-bidi-font-weight:
normal"><span
style="font-size:12.0pt;mso-bidi-font-size:11.0pt;
mso-ansi-language:EN-GB" lang="EN-GB">REFERENCES</span></b></p>
<br>
<span style="mso-ansi-language:EN-GB" lang="EN-GB">[1] J. S.
Ross et al., Electrically tunable excitonic light-emitting
diodes based on monolayer WSe2 p–n junctions, Nat Nanotechnol,
vol. 9, no. 4, pp. 268–272, Apr. 2014.</span><br>
<span style="mso-ansi-language:EN-GB" lang="EN-GB">[2] R. S.
Sundaram et al., Electroluminescence in Single Layer MoS2,
Nano Lett, vol. 13, no. 4, pp. 1416–1421, Apr. 2013.</span><br>
<span style="mso-ansi-language:EN-GB" lang="EN-GB">[3] B. W. H.
Baugher, H. O. H. Churchill, Y. Yang, and P. Jarillo-Herrero,
Optoelectronic devices based on electrically tunable p–n
diodes in a monolayer dichalcogenide, Nat Nanotechnol, vol. 9,
no. 4, pp. 262–267, Apr. 2014.</span><br>
<span style="mso-ansi-language:EN-GB" lang="EN-GB">[4] X. Wang
et al., Defect Heterogeneity in Monolayer WS2 Unveiled by Work
Function Variance, Chemistry of Materials, vol. 31, no. 19,
pp. 7970–7978, Oct. 2019.</span><br>
<span style="mso-ansi-language:EN-GB" lang="EN-GB">[5] A.
Senkić, J. Bajo et al. Effects of CVD growth parameters on
global and local optical properties of MoS2 monolayers,
Materials Chemistry and Physics 296 (2023) 127185.</span><br>
<span style="mso-ansi-language:EN-GB" lang="EN-GB">[6] A. Senkić
et al. Microscopic Investigation of Intrinsic Defects in CVD
Grown MoS2 Monolayers, IoP Nanotechnology, in review.</span>
<div style="color: #000000; font-family: arial, helvetica,
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<div align="justify"><strong>LOCATION:</strong> <span> </span><strong
style="color: #000000; font-family: arial, helvetica,
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letter-spacing: normal; text-indent: 0px; text-transform:
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sans-serif; font-size: 16px; font-style: normal;
letter-spacing: normal; text-indent: 0px; text-transform:
none; white-space: normal; word-spacing: 0px;">Institute of
Physics, 1st wing, big lecture hall + online<br>
</strong></div>
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</div>
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<strong><span lang="EN-GB"><span id="DWT704"><span id="DWT713">Seminar</span></span></span><span
lang="EN-GB"> </span></strong><strong style="color: #000000;
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'century gothic', sans-serif;" lang="EN-GB">: </span></span><font
color="#005a95"><a href="mailto:nsantic@ifs.hr">Neven Šantić</a>
</font>and <u><span class="Object"
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rel="nofollow%20noopener%20noreferrer%20nofollow%20noopener%20noreferrer
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data-mce-style="color: #005a95;
text-decoration: none; cursor: pointer;">Damir
Dominko</a><br>
<br>
Join Zoom Meeting<br>
<a class="moz-txt-link-freetext" href="https://us06web.zoom.us/j/87061512305?pwd=QjcvSWxEOWZoMmxGdGpsVVZnZUxyZz09">https://us06web.zoom.us/j/87061512305?pwd=QjcvSWxEOWZoMmxGdGpsVVZnZUxyZz09</a><br>
<br>
Meeting ID: 870 6151 2305<br>
Passcode: 144767<br>
<br>
</span></span></span></span></span></span></span></span></u></b></div>
<pre class="moz-signature" cols="72">--
Damir Dominko
Research associate
Institute of Physics Zagreb
Bijenicka cesta 46, 02-226
10000 Zagreb, Croatia
office: +385 1 469 8821
cell: +385958172990
e-mail: <a class="moz-txt-link-abbreviated" href="mailto:ddominko@ifs.hr">ddominko@ifs.hr</a></pre>
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