<html><body><div style="font-family: arial, helvetica, sans-serif; font-size: 12pt; color: #000000"><div data-marker="__QUOTED_TEXT__"><div style="font-family: arial, helvetica, sans-serif; font-size: 12pt; color: #000000"><div><div style="font-family: arial, helvetica, sans-serif; font-size: 12pt; color: #000000"><div><div style="font-family: arial, helvetica, sans-serif; font-size: 12pt; color: #000000;"><div style="font-family: arial, helvetica, sans-serif; font-size: 12pt; color: #000000;"><div><div style="color: #000000; font-family: 'times new roman', 'new york', times, serif; font-size: 12pt; text-align: center;"><strong><b><span lang="HR" style="font-size: 16pt; color: black;"><img><img src="cid:fb559ca8379da07816ebeb024a88bd13dae62179@zimbra" data-mce-src="cid:fb559ca8379da07816ebeb024a88bd13dae62179@zimbra"></span></b></strong></div><div style="color: #000000; font-family: 'times new roman', 'new york', times, serif; font-size: 12pt; text-align: center;"><p style="text-align: center; margin: 0px;" align="center"><b><span lang="EN-GB" style="font-family: 'Century Gothic',sans-serif; color: #5f5f5f;">Institut za fiziku, Bijenička cesta 46,</span></b></p><p style="text-align: center; margin: 0px;" align="center"><b><span lang="EN-GB" style="font-family: 'Century Gothic',sans-serif; color: #5f5f5f;">predavaonica u zgradi Mladen Paić</span></b></p><strong><b><span lang="EN-GB" style="font-size: 14pt; font-family: 'Century Gothic',sans-serif; color: #993300;">srijeda, 13. lipnja 2018., u 15:00 sati</span></b><br></strong></div><div style="color: #000000; font-family: 'times new roman', 'new york', times, serif; font-size: 12pt; text-align: center;"><strong></strong> </div><div style="text-align: center;"><span style="color: #55913c; font-family: 'Times New Roman', serif;"><span style="font-size: 21.3333px;"><b>Kinetics of metastable phases of helium. NMR study of metastable liquid inclusions in the quenched solid helium and the mobility of <sup>3</sup>He absorbed on MCM-41</b></span></span></div><div style="text-align: center;"><strong style="color: #000000; font-family: 'times new roman', 'new york', times, serif; font-size: 12pt;"><span lang="EN-GB" style="font-size: 14pt; font-family: 'Century Gothic',sans-serif;">Oleksandr Birchenko</span></strong></div><div style="color: #000000; font-family: 'times new roman', 'new york', times, serif; font-size: 12pt; text-align: center;"><b></b> </div><div style="text-align: center;"><span style="font-family: 'Century Gothic', sans-serif;"><span style="font-size: 14.6667px;"><b>Department of Physics of Quantum Fluids and Crystals</b></span></span></div><div style="text-align: center;"><b style="color: #000000; font-family: 'Century Gothic', sans-serif; font-size: 14.6667px;"> B. Verkin Institute for Low Temperature Physics and Engineering of the National Academy of Sciences of Ukraine, Kharkov, Ukraine</b></div><div style="color: #000000; font-family: 'times new roman', 'new york', times, serif; font-size: 12pt; text-align: center;"><span style="font-size: small; font-family: Arial;"></span> </div><p style="color: #000000; font-family: 'times new roman', 'new york', times, serif; font-size: 12pt; margin: 15px; text-align: justify;"><span style="font-family: arial, helvetica, sans-serif;">Solid helium, as representative of atomic crystals, is the unique modeling object for the investigation of various solid state phase transformations, as well as a wide range of kinetic properties of stable and metastable condensed phases. The advantage of helium is that the condensed phases of helium can be obtained in a controlled manner in a very pure form without impurities, and their properties can easily be changed by the external factors - temperature, pressure, electric or magnetic field. Moreover, the condensed phases of helium are representatives of quantum systems in which the quantum effects such as superfluidity and quantum diffusion are observed.</span></p><p style="color: #000000; font-family: 'times new roman', 'new york', times, serif; font-size: 12pt; margin: 15px; text-align: justify;"><span style="font-family: arial, helvetica, sans-serif;">New data on the properties and conditions of the formation of the metastable disordered phases of helium, crystals growth and annealing and on the processes of diffusion and magnetic relaxation in condensed phases of helium may be used in scientific researches in physics of multicomponent (dispersed) systems and colloidal chemistry. Our research is devoted to the experimental studies of the kinetic properties of the metastable disordered phases of helium and the conditions of their formation.</span></p><p style="color: #000000; font-family: 'times new roman', 'new york', times, serif; font-size: 12pt; margin: 15px; text-align: justify;"><span style="font-family: arial, helvetica, sans-serif;">By precision pressure measurement technique the kinetics of bcc-hcp phase transition in solid <sup>4</sup>He and solid mixture of <sup>3</sup>He in <sup>4</sup>He was studied resulting in the phase diagram. The new kinetic phenomenon was observed – hysteresis of the phase diagram of the weak solid <sup>3</sup>He-<sup>4</sup>He mixture. It was shown that the hysteresis is a result of the influence of <sup>3</sup>He impurities on the nature of the bcc-hcp phase transition.</span></p><p style="color: #000000; font-family: 'times new roman', 'new york', times, serif; font-size: 12pt; margin: 15px; text-align: justify;"><span style="font-family: arial, helvetica, sans-serif;">The kinetics of nucleation under bcc-hcp structural phase transition in solid helium was also studied. It was observed experimentally that in pure solid <sup>4</sup>He both homogeneous and heterogeneous nucleation mechanisms are realized, whereas in weak solid <sup>3</sup>He - <sup>4</sup>He mixture the heterogeneous nucleation regime dominates. For the first time the quantitative description of the nucleation mechanisms in the bcc-hcp phase transition in solid helium was given. The activation energy for homogeneous and heterogeneous nucleation was obtained and it was shown that its frequency is sensitive to the helium crystals quality.</span></p><p style="color: #000000; font-family: 'times new roman', 'new york', times, serif; font-size: 12pt; margin: 15px; text-align: justify;"><span style="font-family: arial, helvetica, sans-serif;">By pulsed NMR technique we detected the presence of metastable liquid inclusions in the quenched hcp 1% <sup>3</sup>Не-<sup>4</sup>Не crystals which were grown by blocking capillary technique. The most intriguing results are the new original NMR data about the possibility of evolution of the metastable liquid inclusions in the hcp matrix of the solid mixture 1% <sup>3</sup>Не-<sup>4</sup>Не in the disordered solid state, which is accompanied by a significant decrease of the speed of spin-spin relaxation and the diffusion coefficient. The diffusion coefficient of <sup>3</sup>He in the liquid inclusions, as they evolve, was measured by a spin echo technique with two probe pulses. It was found that during the evolution, the liquid inclusions are smaller than the diffusion length and diffusion is restricted. The measured coefficient of restricted diffusion made it possible to determine the characteristic size of the inclusions.</span></p><p style="color: #000000; font-family: 'times new roman', 'new york', times, serif; font-size: 12pt; margin: 15px; text-align: justify;"><span style="font-family: arial, helvetica, sans-serif;">The temperature dependence of nuclear magnetic susceptibility of <sup>3</sup>He adsorbed in 2.5 nm 1D channels (300 nm length) of the MCM-41 (Mobile Crystalline Material-41) powder has been studied by pulse NMR method (9.15 MHz). Using the difference of both spin-lattice <em>T<sub>1</sub></em> and spin-spin <em>T<sub>2</sub></em> relaxation times in both “solid” and “fluid” “phases” of adsorbed <sup>3</sup>He, we separated the contribution of each phase to the amplitude of the NMR echo signal. It was shown that magnetic susceptibility of any <sup>3</sup>He phase follows the Curie law, so the temperature in 1.5 monolayers of the condensed helium-3 in MCM-41 corresponds to the measured temperature of the cell.</span></p><p style="color: #000000; font-family: 'times new roman', 'new york', times, serif; font-size: 12pt; margin: 15px; text-align: justify;"><span style="font-family: arial, helvetica, sans-serif;"></span><br></p></div><div style="color: #000000; font-family: arial, helvetica, sans-serif; font-size: 12pt; text-align: left;"><b><span lang="EN-GB" style="font-size: 12pt; font-family: 'Century Gothic',sans-serif;"><b><span lang="EN-GB" style="font-size: 11pt; font-family: 'Century Gothic',sans-serif;"> </span></b></span></b><b><span lang="EN-GB" style="font-size: 12pt; font-family: 'Century Gothic',sans-serif;"><b><span lang="EN-GB" style="font-size: 11pt; font-family: 'Century Gothic',sans-serif;">Voditelji seminara IF-a: <a href="mailto:hrvoje@ifs.hr" target="_blank">Hrvoje Skenderović</a> i <a href="mailto:damirs@ifs.hr" target="_blank">Damir Starešinić</a></span></b></span></b></div></div></div></div></div></div></div><br></div></div></body></html>