<html><head><style type='text/css'>p { margin: 0; }</style></head><body><div style='font-family: Times New Roman; font-size: 12pt; color: #000000'><br>Postovani,<br>U najavi seminara koju sam prethodno poslala potkrala se greska u poveznici na osobnu stranicu kolege<br>Vdovica. Ispricavam se svima i saljem ispravljenu najavu.<br>Srdacan pozdrav<br>Vlasta Horvatic<br>=======================================<br><div style="color: rgb(0, 0, 0); font-weight: normal; font-style: normal; text-decoration: none; font-family: Helvetica,Arial,sans-serif; font-size: 12pt;"><b></b><style> { margin: 0; }</style><div style="font-family: Times New Roman; font-size: 12pt; color: rgb(0, 0, 0);"><br><div style="color: rgb(0, 0, 0); font-weight: normal; font-style: normal; text-decoration: none; font-family: Helvetica,Arial,sans-serif; font-size: 12pt;"><style>p { margin: 0; }</style><div style="font-family: Times New Roman; font-size: 12pt; color: rgb(0, 0, 0);"><div style="color: rgb(0, 0, 0); font-weight: normal; font-style: normal; text-decoration: none; font-family: Helvetica,Arial,sans-serif; font-size: 12pt;"><style>p { margin: 0; }</style><div style="font-family: Times New Roman; font-size: 12pt; color: rgb(0, 0, 0);"><br><div style="color: rgb(0, 0, 0); font-weight: normal; font-style: normal; text-decoration: none; font-family: Helvetica,Arial,sans-serif; font-size: 12pt;"><style>p { margin: 0; }</style><div style="font-family: Times New Roman; font-size: 12pt; color: rgb(0, 0, 0);"><div style="color: rgb(0, 0, 0); font-weight: normal; font-style: normal; text-decoration: none; font-family: Helvetica,Arial,sans-serif; font-size: 12pt;"><div style="font-family: Times New Roman; font-size: 12pt; color: rgb(0, 0, 0);"><div style="color: rgb(0, 0, 0); font-weight: normal; font-style: normal; text-decoration: none; font-family: Helvetica,Arial,sans-serif; font-size: 12pt;"><div style="font-family: Times New Roman; font-size: 12pt; color: rgb(0, 0, 0);"><div style="color: rgb(0, 0, 0); font-weight: normal; font-style: normal; text-decoration: none; font-family: Helvetica,Arial,sans-serif; font-size: 12pt;"><br><style>p { margin: 0; }</style><div style="font-family: Times New Roman; font-size: 12pt; color: rgb(0, 0, 0);"><div style="text-align: center;"><img src="cid:0d3929e176f70a34794fe877421961aa823975e6@zimbra"></div><style>
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<p class="MsoNormal" style="margin: 3pt 0cm; text-align: center;" align="center"><b style=""><span style="font-family: "Century Gothic"; color: rgb(95, 95, 95);">Institut za
fiziku, Bijenička cesta 46,</span></b></p>
<p class="MsoNormal" style="margin: 3pt 0cm; text-align: center;" align="center"><b style=""><span style="font-family: "Century Gothic"; color: rgb(95, 95, 95);">predavaonica
u zgradi Mladen Paić</span></b></p>
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</style><b style="font-family: arial,helvetica,sans-serif;"><span style="font-size: 14pt; color: rgb(153, 51, 0);">u četvrtak, 20. prosinca 2012. u 15:00 sati</span></b><b style=""><span style="font-size: 14pt; font-family: "Century Gothic"; color: rgb(153, 51, 0);"></span></b><span style="font-family: "Century Gothic";"></span></p>
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<h1><span style="font-size: 16pt; color: rgb(85, 145, 60);" lang="HR">Primjena
ultrabrze spektroskopije u proučavanju molekularnog prijenosa energije</span><span style="font-size: 16pt; color: rgb(85, 145, 60);" lang="HR"></span></h1>
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sc. Silvije Vdovi</span><span style="font-size: 14pt;" lang="HR">ć</span></b><b><span style="font-size: 14pt;"></span></b></p>
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za fiziku, Bijenička 46, Zagreb</span></b><b><span style="font-family: "Century Gothic";" lang="EN-US"></span></b></p>
<div style="text-align: center;"><b><i><span style="font-size: 11pt; font-family: "Arial Unicode MS";">E-mail:</span><span style="font-size: 11pt; font-family: "Century Gothic";"> </span><span class="object"><u><span style="font-size: 11pt; font-family: "Arial Unicode MS"; color: blue;">silvije@ifs.hr</span></u></span></i></b></div><p style="margin: 5.95pt 0cm 0.0001pt; text-align: center;" align="center"><b><i><u><span style="font-size: 11pt; font-family: "Century Gothic";"><a href="mailto:ajbotha@scientia.up.ac.za" target="_blank"></a></span></u></i></b><b><span style="font-size: 11pt; font-family: "Century Gothic"; color: black;"></span></b></p>
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</p><p class="MsoBodyText3">Proučavanje procesa relaksacije i prijenosa energije u
pigmentima koji sudjeluju u procesu fotosinteze važno je za razumijevanje iznimne
brzine i efikasnosti fotosintetske pretvorbe energije. Ultrabrza spektroskopija
omogućava mjerenje procesa relaksacije u prirodnim, ali i umjetno stvorenim
molekulama što je zanimljivo s aspekta razvoja organskih solarnih ćelija, novih
izvora svjetlosti itd. </p>
<p class="MsoNormal" style="text-align: justify; line-height: 13pt;"><b><span style="font-family: "Arial Unicode MS";"> </span></b></p>
<p class="MsoNormal" style="text-align: justify; line-height: 13pt;"><b><span style="font-family: "Arial Unicode MS";">Mjerenjem
tranzijentne apsorpcije kromofore moguće je odrediti relaksacijsku kinetiku, no
u slučajevima u kojima se pojavljuju tzv ‘tamna stanja’ ili ukoliko se
spektralni potpisi pojedinih stanja kroz koja se energija transferira
preklapaju, potrebno je globalno analizirati izmjerene vremenski ovisne
spektre. Globalna analiza u principu zahtijeva poznavanje relaksacijskog
modela. U nekim slučajevima moguće je koristiti <i style="">model-free</i> analizu kao što je na primjer MCR-ALS multivarijacijska
analiza. Mjerenje anizotropije apsorpcije ili fluorescencije daje dodatne
korisne informacije bitne za uspješno određivanje relaksacijskog modela. </span></b></p>
<p class="MsoNormal" style="text-align: justify; line-height: 13pt;"><b><span style="font-family: "Arial Unicode MS";"> </span></b></p>
<p class="MsoNormal" style="text-align: justify; line-height: 13pt;"><b><span style="font-family: "Arial Unicode MS";">Na
seminaru će biti prikazani rezultati analize tranzijentne apsorpcije all-trans
beta karotena kojima se pokušalo potvrditi postojanje kontroverznog <i style="">S*</i> tamnog stanja smještenog izme</span></b><b><span style="font-family: "Arial Unicode MS";">đ</span></b><b><span style="font-family: "Arial Unicode MS";">u dobro poznatog prvog i drugog singletnog
pobu</span></b><b><span style="font-family: "Arial Unicode MS";">đ</span></b><b><span style="font-family: "Arial Unicode MS";">enog
stanja beta karotena. Na jednom drugom primjeru kromofore s razgranatom
strukturom (heksamer) rezultati globalne analize tranzijentne apsorpcije i
mjerenja anizotropije omogućila su detaljan uvid u kompleksni relaksacijski mehanizam.
Struktura heksamera vrlo je slična strukturi pigmenta alofikocijanina (APC). Inicijalno
pobuđena delokalizirana ekscitonska stanja nastala zbog snažnog vezanja dipolnih
momenata prijelaza dviju kromofora unutar svake od tri grane heksamera lokaliziraju
se u jednoj od grana. Istovremeno dolazi do ekscitonske dekoherencije. Slijedi
relaksacija u dugoživuće ekscimersko stanje koje se formira u grani sa najnižom
energijom.</span></b></p>
<br><b><span style="font-size: 11pt; font-family: "Arial Unicode MS";"></span></b><p></p>
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<b><span style="font-size: 10pt; font-family: "Century Gothic";"> </span></b>
<p class="MsoNormal"><b><span style="font-size: 10pt; font-family: "Century Gothic";"><span style=""> </span></span></b><b><span style="font-size: 11pt; font-family: "Century Gothic";"><br></span></b></p><p class="MsoNormal"><b><span style="font-size: 11pt; font-family: "Century Gothic";">Voditelji
seminara IF-a: Vlasta Horvatić i Osor Bari</span></b><b><span style="font-size: 11pt; font-family: "Century Gothic";" lang="HR">šić</span></b><span style="" lang="HR"></span></p>
<br><b><span style="font-size: 11pt; font-family: "Century Gothic"; color: blue;"></span></b><p></p>
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<p class="MsoNormal"><b><span style="font-size: 11pt; font-family: "Century Gothic";"><br></span></b></p>
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